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91.
报道Ar^q Ne(q=8,9,11,12)碰撞体系中多电子转移过程,得到了多组实验测量电荷交换截面数据,讨论入射离子电荷交换截面、反冲离子产生截面与入射离子电荷态、能量以及散射离子电荷态的关系,并且将实验结果与Ar^q Ar碰撞体系进行对比研究。在修正分子库仑过垒模型的基础上,对实验现象做了合理的解释。 相似文献
92.
Qing Shi Dong Yang Yanlei Su Jian Li Zhongyi Jiang Yanjun Jiang Weikang Yuan 《Journal of nanoparticle research》2007,9(6):1205-1210
Lipase from Candida rugosa was covalently anchored onto acid-treated multi-walled carbon nanotubes (MWNTs) through a self-catalytic mechanism. A variety
of characterization techniques including FTIR, Raman spectroscopy, and XPS were employed to demonstrate the formation of the
ester linkage between lipase and MWNTs. The MWNTs-lipase biocomposites showed significantly increased solubility in some common-used
organic solvents, such as THF, DMF and chloroform. This study may offer a novel and facile route for covalent modification
of carbon nanotubes, and expand the potential utilization of both lipases and MWNTs in the fields of biocatalyst and biosensor. 相似文献
93.
Alpeshkumar K. Malde Santosh A. Khedkar Evans C. Coutinho 《Journal of Physical Organic Chemistry》2007,20(2):151-160
Modification of peptides to produce peptidomimetics is of great interest, with the aim of designing potent, selective, and metabolically stable analogs having certain conformational properties. Organoboranes have been reported in the literature with a wide range of therapeutic applications. One of the therapeutically important class of molecules is amine‐carboxyboranes derived from amino acids by replacement of the Cα atom of an amino acid/peptide by boron. The conformational preferences of these peptides, with respect to backbone ω, ?, and ψ torsion angles, have been investigated by theoretical calculations. The amide bond in these molecules has the same geometry in the ground and transition states as the natural peptides. However, the boron isosteres of glycine and alanine peptides are less structured than their natural derivatives, but are distinguished by structures with a positive value for the ? angle, which is normally disfavored for natural peptides. This property could be used to build peptides with a geometry not usually seen in natural peptides. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
94.
M. C. Crabb 《Journal of Fixed Point Theory and Applications》2007,2(2):171-193
We describe an equivariant version (for actions of a finite group G) of Dold’s index theory, [10], for iterated maps. Equivariant Dold indices are defined, in general, for a G-map U → X defined on an open G-subset of a G-ANR X (and satisfying a suitable compactness condition). A local index for isolated fixed-points is introduced, and the theorem
of Shub and Sullivan on the vanishing of all but finitely many Dold indices for a continuously differentiable map is extended
to the equivariant case. Homotopy Dold indices, arising from the equivariant Reidemeister trace, are also considered.
相似文献
95.
Average Atom Model in Hot Plasmas 总被引:4,自引:2,他引:2
Average Atom Model in Hot PlasmasAverageAtomModelinHotPlasmas¥YuanJianhui;SunYongsheng;ZhengShaotang(InstituteofAppliedPhysic... 相似文献
96.
Partially supportted by Grant MM-22/1991 of MESC 相似文献
97.
98.
多线性Calderón-Zygmund算子的加权有界性 总被引:2,自引:0,他引:2
建立了多线性Calderón-Zygmund算子在比幂权空间更一般的Herz空间和Herz型Hardy空间上的有界性.作为推论,得到了该算子的幂权估计.在这些幂权估计中,权指标可以突破Ap权的指标限制,显示出和经典Calderón-Zygmund算子本质的区别. 相似文献
99.
Ke Sha Dongshuang Li Yapeng Li Xiaotian Liu Shuwei Wang Jingqi Guan Jingyuan Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5037-5049
Amphiphilic diblock copolymer polycaprolactone‐block‐poly(glycidyl methacrylate) (PCL‐b‐PGMA) was synthesized via enzymatic ring‐opening polymerization (eROP) and atom transfer radical polymerization (ATRP). Methanol first initiated eROP of ?‐caprolactone (?‐CL) in the presence of biocatalyst Novozyme‐435 under anhydrous conditions. The resulting monohydroxyl‐terminated polycaprolactone (PCL–OH) was subsequently converted to a bromine‐ended macroinitiator (PCL–Br) for ATRP by esterification with α‐bromopropionyl bromide. PCL‐b‐PGMA diblock copolymers were synthesized in a subsequent ATRP of glycidyl methacrylate (GMA). A kinetic analysis of ATRP indicated a living/controlled radical process. The macromolecular structures were characterized for PCL–OH, PCL–Br, and the block copolymers by means of nuclear magnetic resonance, gel permeation chromatography, and infrared spectroscopy. Differential scanning calorimetry and wide‐angle X‐ray diffraction analyses indicated that the copolymer composition (?‐CL/GMA) had a great influence on the thermal properties. The well‐defined, amphiphilic diblock copolymer PCL‐b‐PGMA self‐assembled into nanoscale micelles in aqueous solutions, as investigated by dynamic light scattering and transmission electron microscopy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5037–5049, 2007 相似文献
100.
The present paper deals with the study of a Durrmeyer-type integral modification of certain modified Baskakov operators. Here
we study simultaneous approximation properties for these operators by using the iterative combinations. We obtain an asymptotic
formula and an error estimation in terms of higher order modulus of continuity for these operators.
相似文献